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Product FLORAL

Print Date 02/10/2011 Page 1 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : FLORALOL

Sales ID : 00062974

MSDS Number : R00000221780

Product Use Description : Fragrance Ingredient

Company : IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ 12 12580

Telephone : +34964470212

Telefax : +34964473411

Emergency telephone : +34 964 470 212

SECTION 2 HAZARDS IDENTIFICATION

OSHA Hazards : Mild skin irritant

Mild eye irritant

Carcinogenicity:

No component of this product present at levels greater than or equal to 0.1% is identified as probable,

possible or confirmed human carcinogen by IARC.

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen

or potential carcinogen by OSHA.

No component of this product present at levels greater than or equal to 0.1% is identified as a known or

anticipated carcinogen by NTP.

No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen

or potential carcinogen by ACGIH.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

Component CAS-No.

Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product FLORALOL

Print Date 02/10/2011 Page 2 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

3,5-dimethylcyclohexene-1-methanol 67634-16-6

2,6-di-tert-butyl-p-cresol 128-37-0

SECTION 4. FIRST AID MEASURES

First aid procedures

Inhalation : Remove from exposure site to fresh air and keep at rest.

Obtain medical advice.

Skin contact : Remove contaminated clothes. Wash thoroughly with water

(and soap). Contact physician if symptoms persist.

Eye contact : Flush immediately with water for at least 15 minutes. Contact

physician if symptoms persist.

Ingestion : Rinse mouth with water and obtain medical advice.

SECTION 5. FIRE-FIGHTING MEASURES

Flammable properties

Flash point : 201.20 °F (94.00 °C)

Fire fighting

Suitable extinguishing media : Use water spray, dry chemical, carbon dioxide or appropriate

foam.

Protective equipment and precautions for firefighters

Special protective equipment

for fire-fighters

: Wear NIOSH approved self-contained breathing apparatus and

full protective clothing when fighting fires involving chemicals.

Use water spray to cool containers exposed to fire.

Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product FLORALOL

Print Date 02/10/2011 Page 3 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Avoid inhalation and contact with skin and eyes. A selfcontained

breathing apparatus is recommended in case of a

major spill.

Environmental precautions : Keep away from drains, surface- and groundwater and soil.

Methods for containment /

Methods for cleaning up

: Clean up spillage promptly. Remove ignition sources. Provide

adequate vent spillages should be contained by use of sand or

inert powder and disposed

SECTION 7. HANDLING AND STORAGE

Handling : Avoid excessive inhalation of concentrated vapors. Follow

good manufacturing practices for housekeeping and personal

hygiene. Wash any exposed skin immediately after any

chemical contact, before breaks and meals, and at the end of

each work period. Contaminated clothing and shoes should be

thoroughly cleaned before re-use.

If appropriate, procedures used during the handling of this

material should also be used when cleaning equipment or

removing residual chemicals from tanks or other containers,

especially when steam or hot water is used, as this may

increase vapor concentrations in the workplace air. Where

chemicals are openly handled, access should be restricted to

properly trained employees.

Keep all heated processes at the lowest necessary

temperature in order to minimize emissions of volatile

chemicals into the air.

Advice on protection against

fire and explosion

: Keep away from ignition sources and naked flame.

Requirements for storage areas

and containers

: Store in a cool, dry, ventilated area away from heat sources.

Keep containers upright and tightly closed when not in use.

Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product FLORALOL

Print Date 02/10/2011 Page 4 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures

Engineering measures : Where feasible, isolate mixing rooms and other areas where

this material is used or openly handled. Maintain these areas

under negative air pressure relative to the rest of the plant.

Where feasible, use closed systems to transfer and process

this material

Personal protective equipment

Respiratory protection : Use local exhaust ventilation around open tanks and other

open sources of potential exposures in order to avoid

excessive inhalation, including places where this material is

openly weighed or measured. In addition, use general dilution

ventilation of the work area to eliminate or reduce possible

worker exposures.

No respiratory protection is required during normal operations

in a workplace where engineering controls such as adequate

ventilation, etc. are sufficient.

If engineering controls and safe work practices are not

sufficient, an approved, properly fitted respirator with organic

vapor cartridges or canisters and particulate filters should be

used:

a)while engineering controls and appropriate safe work

practices and/or procedures are being implemented; or

b)during short term maintenance procedures when

engineering controls are not in normal operation or are not

sufficient; or

c)if normal operational workplace vapor concentration in the

air is increased due to heat ;

d)during emergencies; or

e)if engineering controls and operational practices are not

sufficient to reduce airborne concentrations below an

Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product FLORALOL

Print Date 02/10/2011 Page 5 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

established occupational exposure limit.

Hygiene measures : To the extent deemed appropriate, implement pre-placement

and regularly scheduled ascertainment of symptoms and

spirometry testing of lung function for workers who are

regularly exposed to this material.

To the extent deemed appropriate, use an experienced air

sampling expert to identify and measure volatile chemicals

that could be present in the workplace air to determine

potential exposures and to ensure the continuing

effectiveness of engineering controls and operational

practices to minimize exposure.

Protective measures : In December 2003, the National Institute for Occupational

Safety and Health ("NIOSH") published an Alert on preventing

lung disease in workers who use or make flavorings [NIOSH

Publication Number 2004-110].

In August 2004, the United States Flavor and Extract

Manufacturers Association (FEMA) issued a report entitled

"Respiratory Safety in the Flavor Manufacturing Workplace".

Both of these reports provide recommendations for reducing

employee exposure and for medical surveillance in the

workplace. The recommendations in these reports are

generally applicable to the use of any chemical in the

workplace and you are strongly urged to review both of these

reports.

The report published by FEMA also contains a list of "high

priority" chemicals. If any of these chemicals are present in

this product at a concentration >= 1.0% due to an intentional

addition by IFF, the chemical(s) will be identified in this safety

data sheet.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

Physical state : liquid

Colour : colorless to pale yellow

Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product FLORALOL

Print Date 02/10/2011 Page 6 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

Odour : Conforms to Standard

Safety data

Flash point : 201.20 °F (94.00 °C)

Vapour pressure : Note: not determined

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Remarks: Presents no significant reactivity hazard, by itself or

in contact with water. Avoid contact with strong acids, alkali or

oxidizing agents.

Hazardous decomposition

products

: Note: Carbon monoxide and unidentified organic compounds

may be formed during combustion.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute dermal toxicity : LD50 rabbit

Dose: 2,000 mg/kg

Skin irritation (Component) : Component:

rabbit

Result: No skin irritation

human

Result: No skin irritation

Method: repeated insult patch test

Eye irritation(Component) : Component:

rabbit

Result: Mild eye irritation

Sensitisation (Component) : Component:

Test substance: 0.0%

human

Result: Did not cause sensitization on laboratory animals.

Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product FLORALOL

Print Date 02/10/2011 Page 7 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

Test substance: 10%

Repeated dose

toxicity(Component)

: Component:

SECTION 12. ECOLOGICAL INFORMATION

SECTION 13. DISPOSAL CONSIDERATIONS

Contaminated packaging : Place material into sealed containers and dispose of in

accordance with local, state and federal regulations.

SECTION 14. TRANSPORT INFORMATION

DOT Not dangerous goods

IATA Not dangerous goods

IMDG Not dangerous goods

SECTION 15. REGULATORY INFORMATION

OSHA Hazards : Mild skin irritant, Mild eye irritant

SARA 311/312 Hazards : Acute Health Hazard

California Prop. 65

Components

: This product does not contain any chemicals known to State of

California to cause cancer, birth, or any other reproductive

defects.

HMIS Classification : Health Hazard: 1

Flammability: 1

Physical and chemical hazards: 0

Material Safety Data Sheet

INTERNATIONAL FLAVORS & FRAGRANCES

Product FLORALOL

Print Date 02/10/2011 Page 8 (8)

Version : 1

Revision Date : 07/12/2007

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

IFF Benicarló, S.A.

Avda. Felipe Klein 2

BENICARLÓ, 12

Telephone: +34964470212 Telefax: +34964473411

SECTION 16. OTHER INFORMATION

Further information

The information in this MSDS was obtained from current and reliable sources. However the data is

provided without any warrant, expressed or implied, regarding its correctness or accuracy. Since the

use, handling, storage and disposal of this product are beyond IFF control, it is the responsibility of the

user both to determine safe conditions for the use of this product and to assume liability of loss,

damage, or expense arising out of the product's improper use. No warranty expressed or implied

regarding the product described herein shall be created by or inferred from any statement or omission

in this MSDS. Various Federal, State or Provincial agencies may have specific regulations concerning

the transportation, handling, storage, use, or disposal of this product which may not be reflected in this

MSDS. The user should review these regulations to ensure full compliance.