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Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 1 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : CITRONELLOL COEUR MSDS Number : R00000217407 Product Use Description : Fragrance Ingredient
Company : IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone : (732) 264-4500 Telefax : (732) 335-2551 Emergency telephone : +1 800 424 9300
SECTION 2 HAZARDS IDENTIFICATION
Emergency Overview OSHA Hazards : Skin sensitiser Moderate skin irritant Moderate eye irritant
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 2 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
Component CAS-No.
3,7-Dimethyl-6-octen-1-ol; 3,7-Dimethyl-6-octen-1-ol, 6-Octen-1-ol, 3,7- dimethyl-
106-22-9
1-Octanol, 3,7-dimethyl- 106-21-8
2,6-Octadien-1-ol, 3,7-dimethyl-, (2E)- 106-24-1
2,6-Octadien-1-ol, 3,7-dimethyl-, (2Z)- 106-25-2
SECTION 4. FIRST AID MEASURES
First aid procedures Inhalation : Remove from exposure site to fresh air and keep at rest. Obtain medical advice.
Skin contact : Remove contaminated clothes. Wash thoroughly with water (and soap). Contact physician if symptoms persist.
Eye contact : Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist.
Ingestion : Rinse mouth with water and obtain medical advice.
SECTION 5. FIRE-FIGHTING MEASURES
Flammable properties Flash point : 212.00 °F (100.00 °C)
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 3 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
Fire fighting Suitable extinguishing media : Use water spray, dry chemical, carbon dioxide or appropriate foam.
Protective equipment and precautions for firefighters Special protective equipment for fire-fighters : Wear NIOSH approved self-contained breathing apparatus and full protective clothing when fighting fires involving chemicals. Use water spray to cool containers exposed to fire.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Avoid inhalation and contact with skin and eyes. A self- contained breathing apparatus is recommended in case of a major spill.
Environmental precautions : Keep away from drains, surface- and groundwater and soil.
Methods for containment / Methods for cleaning up
: Clean up spillage promptly. Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Gross spillages should be contained by use of sand or inert powder and disposed of according to the local regulations.
SECTION 7. HANDLING AND STORAGE
Handling : Avoid excessive inhalation of concentrated vapors. Follow good manufacturing practices for housekeeping and personal hygiene. Wash any exposed skin immediately after any chemical contact, before breaks and meals, and at the end of each work period. Contaminated clothing and shoes should be thoroughly cleaned before re-use.
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 4 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
If appropriate, procedures used during the handling of this material should also be used when cleaning equipment or removing residual chemicals from tanks or other containers, especially when steam or hot water is used, as this may increase vapor concentrations in the workplace air. Where chemicals are openly handled, access should be restricted to properly trained employees. Keep all heated processes at the lowest necessary temperature in order to minimize emissions of volatile chemicals into the air.
Advice on protection against fire and explosion
: Keep away from ignition sources and naked flame.
Requirements for storage areas and containers
: Store in a cool, dry, ventilated area away from heat sources. Keep containers upright and tightly closed when not in use.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters
Engineering measures Engineering measures : Where feasible, isolate mixing rooms and other areas where this material is used or openly handled.  Maintain these areas under negative air pressure relative to the rest of the plant. Where feasible, use closed systems to transfer and process this material
Personal protective equipment Eye protection : Use tight-fitting goggles, face shield or safety glasses with side shields if eye contact might occur.
Hand protection : Avoid skin contact. Use chemically resistant gloves.
Respiratory protection : Use local exhaust ventilation around open tanks and other
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 5 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured.  In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. No respiratory protection is required during normal operations in a workplace where engineering controls such as adequate ventilation, etc. are sufficient.
If engineering controls and safe work practices are not sufficient, an approved, properly fitted respirator with organic vapor cartridges or canisters and particulate filters should be used:
a)while engineering controls and appropriate safe work practices and/or procedures are being implemented; or b)during short term maintenance procedures  when engineering controls are not in normal operation or are not sufficient; or c)if normal operational workplace vapor concentration in the air is increased due to heat ; d)during emergencies; or e)if engineering controls and operational practices are not sufficient to reduce airborne concentrations below an established occupational exposure limit.
Hygiene measures : To the extent deemed appropriate, implement pre-placement and regularly scheduled ascertainment of symptoms and spirometry testing of lung function for workers who are regularly exposed to this material. To the extent deemed appropriate, use an experienced air sampling expert to identify and measure volatile chemicals that could be present in the workplace air to determine potential exposures and to ensure the continuing effectiveness of engineering controls and operational practices to minimize exposure.
Protective measures : In December 2003, the National Institute for Occupational Safety and Health ("NIOSH") published an Alert on preventing
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 6 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
lung disease in workers who use or make flavorings [NIOSH Publication Number 2004-110]. In August 2004, the United States Flavor and Extract Manufacturers Association (FEMA) issued a report entitled "Respiratory Safety in the Flavor Manufacturing Workplace". Both of these reports provide recommendations for reducing employee exposure and for medical surveillance in the workplace. The recommendations in these reports are generally applicable to the use of any chemical in the workplace and you are strongly urged to review both of these reports. The report published by FEMA also contains a list of "high priority" chemicals. If any of these chemicals are present in this product at a concentration >= 1.0% due to an intentional addition by IFF, the chemical(s) will be identified in this safety data sheet.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Physical state : liquid Colour : colorless to pale yellow
Odour : Conforms to standard
Safety data Flash point : 212.00 °F (100.00 °C)
Vapour pressure : .02 hPa (0.02 mmHg) Note: Calculated
Relative density (20 °C) : 0.8510 - 0.8590
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 7 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
SECTION 10. STABILITY AND REACTIVITY
Chemical stability : Remarks: Presents no significant reactivity hazard, by itself or in contact with water. Avoid contact with strong acids, alkali or oxidizing agents.
Hazardous decomposition products
: Note: Carbon monoxide and unidentified organic compounds may be formed during combustion.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : Acute toxicity estimate Dose: 4,477.97 mg/kg Method: Calculation method
Acute oral toxicity (Component) : Component: 106-22-9 LD50 rat Dose: 3,450 mg/kg Remarks: RIFM
Component: 106-21-8 LD50 rat Dose: > 5,000 mg/kg Remarks: RIFM
Component: 106-24-1 LD50 rat Dose: 4,800 mg/kg Remarks: RIFM
Component: 106-25-2 LD50 rat Dose: 4,500 mg/kg Remarks: RIFM
Acute dermal toxicity : Acute toxicity estimate
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 8 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
Dose: 2,906.64 mg/kg Method: Calculation method
Acute dermal toxicity (Component)
: Component: 106-22-9 LD50 rabbit Dose: 2,650 mg/kg
Component: 106-21-8 LD50 rabbit Dose: 2,400 mg/kg
Component: 106-24-1 LD50 rabbit Dose: > 5,000 mg/kg
Component: 106-25-2 LD50 rabbit Dose: > 5,000 mg/kg
Skin irritation (Component) : Component: 106-21-8 human Result: No skin irritation Method: closed patch test Exposure time: 48 h rabbit Result: irritating
Component: 106-25-2 human Result: No skin irritation Method: closed patch test Exposure time: 48 h rabbit Result: Skin irritation Exposure time: 24 h
Sensitisation (Component) : Component: 106-21-8 Test substance: 0.0% maximisation study human
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 9 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
Result: Did not cause sensitization on laboratory animals. Test substance: 8.0% in petrolatum
Component: 106-24-1 maximisation study human Result: Did not cause sensitization on laboratory animals. Test substance: 6.0% in petrolatum
Component: 106-25-2 maximisation study human Result: Did not cause sensitization on laboratory animals. Test substance: 4.0% in petrolatum
Repeated dose toxicity(Component)
: Component: 106-21-8
Component: 106-24-1
Component: 106-25-2
SECTION 12. ECOLOGICAL INFORMATION
Component: 106-21-8 DIMETHYL OCTANOL
Toxicity to daphnia and other aquatic invertebrates.: EC50 Species: Dose:  3.6 mg/l Exposure time: 48 h
SECTION 13. DISPOSAL CONSIDERATIONS
Contaminated packaging : Place material into sealed containers and dispose of in accordance with local, state and federal regulations.
Material Safety Data Sheet INTERNATIONAL  FLAVORS  &  FRAGRANCES
Product CITRONELLOL COEUR
Print Date 02/08/2011 Page 10 (10)
Version :  2 Revision Date :  10/08/2010
IFF Inc. 600 Highway 36 Hazlet NJ  07730
IFF Inc. 600 Highway 36 Hazlet NJ  07730
Telephone: +17322644500 Telefax: +17323352551
SECTION 14. TRANSPORT INFORMATION
DOT Not dangerous goods
IATA Not dangerous goods
IMDG Not dangerous goods
SECTION 15. REGULATORY INFORMATION
OSHA Hazards : Skin sensitiser, Moderate skin irritant, Moderate eye irritant SARA 311/312 Hazards : Acute Health Hazard
HMIS Classification : Health hazard: 2 Flammability: 1 Physical and chemical hazards: 0
SECTION 16. OTHER INFORMATION
Further information The information in this MSDS was obtained from current and reliable sources. However the data is provided without any warrant, expressed or implied, regarding its correctness or accuracy. Since the use, handling, storage and disposal of this product are beyond IFF control, it is the responsibility of the user both to determine safe conditions for the use of this product and to assume liability of loss, damage, or expense arising out of the product's improper use. No warranty expressed or implied regarding  the product described herein shall be created by or inferred from any statement or omission in this MSDS. Various Federal, State or Provincial agencies may have specific regulations concerning the transportation, handling, storage, use, or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance.