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SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 1 of 10 Print Date: 02-20-2018

1. IDENTIFICATION Product Description: CANTRYL® CAS # 15373-31-6
Othermeans of identification Vigon Item # 502470 Recommendeduse Concentrated aromatic ingredient which may be used fragrance compounds according to legal and IFRA guidelines. Recommendedrestrictions For Manufacturing Use Only
Company 24 Hour Emergency Response Information Vigon International, Inc. INFOTRAC (ACCT# 78928); 1-800-535-5053 WITHIN THE U.S.A.
127 Airport Road
1-352-323-3500 OUTSIDE THE U.S.A.
E. Stroudsburg, PA 18301 For information call: 570-476-6300 Web Site: www.vigon.com Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name Vigon International, Inc.
Address 127 Airport Road
E. Stroudsburg, PA 18301
United States
Telephone For information call: 570-476-6300
Website www.vigon.com
E-mail Not available.
Emergency phone number INFOTRAC (ACCT# 78928);
1-800-535-5053 WITHIN THE U.S.A.
1-352-323-3500 OUTSIDE THE U.S.A.

2. HAZARD(S) IDENTIFICATION Physical hazards Flammable liquids Health hazards Acute toxicity, oral Skin corrosion/irritation Environmental hazards Not classified. Category 4 Category 5 Category 2
Label elements


Signal word Warning Hazardstatement Combustible liquid. May be harmful if swallowed. Causes skin irritation.

SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 2 of 10 Print Date: 02-20-2018

Precautionary statement
Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection.
Response IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. In case of fire: Use appropriate media to extinguish.
Storage Store in a well-ventilated place. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplementalinformation 100% of the mixture consists of component(s) of unknown acute dermal toxicity. 100% of the mixture consists of component(s) of unknown acute inhalation toxicity. 100% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 100% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
3. COMPOSITION/INFORMATION ONINGREDIENTS
Substances Chemicalname Commonnameandsynonyms CASnumber %
2,2,3-Trimethylcyclopent-3-2-(2,2,3-15373-31-6 100
enylacetonitrile trimethyl-1-cyclopent-3-enyl)acetonitrile 3-Cyclopentene-1-acetonitrile, 2,2,3-trimethyl-2,2,3-Trimethylcyclopent-3-enylacetonitril e

4. FIRST-AID MEASURES Inhalation
Skin contact
Eye contact
Ingestion
Mostimportant symptoms/effects, acuteand delayed
Indication of immediate medical attention andspecial treatment needed
General information

If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. For breathing difficulties, oxygen may be necessary. Call a physician if symptoms develop or persist.
Take off immediately all contaminated clothing. Get medical attention if irritation develops and
persists. Wash skin thoroughly with soap and water for several minutes. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Promptly wash eyes with plenty of water while lifting the eye lids.
Call a physician or poison control center immediately. If swallowed, rinse mouth with water (only if the person is conscious). Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs.
Direct contact with eyes may cause temporary irritation. Skin irritation. May cause redness and pain.
Not available.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.


SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 3 of 10 Print Date: 02-20-2018


5. FIRE-FIGHTING MEASURES
Suitableextinguishingmedia Water spray, fog, CO2, dry chemical, or alcohol resistant foam. Unsuitableextinguishingmedia Do not use a solid water stream as it may scatter and spread fire. Specifichazardsarisingfrom Fire may produce irritating, corrosive and/or toxic gases.
the chemical Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with andprecautionsforfirefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Structural firefighters protective clothing will only provide limited protection. Wear self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode when fighting fires. Firefighting In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and equipment/instructions consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Water runoff can cause environmental damage. Ventilate closed spaces before
entering them. Keep run-off water out of sewers and water sources. Dike for water control. Specificmethods Use water spray to cool unopened containers. Generalfirehazards Static charges generated by emptying package in or near flammable vapor may cause flash fire.

6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Methodsandmaterialsfor containmentand cleaningup Keep unnecessary personnel away. Eliminate all sources of ignition. Avoid contact with skin or inhalation of spillage, dust or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them.

Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand or diatomaceous earth, commercial sorbents, or recover using pumps.
The product is immiscible with water and will spread on the water surface.
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Prevent product from entering drains. Absorb in vermiculite, dry sand or earth and place into containers.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.
Never return spills in original containers for re-use. This material and its container must be disposed of as hazardous waste. Collect and dispose of spillage as indicated in section 13 of the SDS.
Environmentalprecautions Retain and dispose of contaminated wash water. Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water.


SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 4 of 10 Print Date: 02-20-2018


7. HANDLINGAND STORAGE
Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Wash thoroughly after handling.
Conditions for safe storage, Keep container closed. Handle containers with care. Open slowly in order to control possible including any incompatibilities pressure release. Store in a cool, well-ventilated area.
8. EXPOSURECONTROLS/PERSONALPROTECTION Occupationalexposurelimits This substance has no PEL, TLV, or other recommended exposure limit. Biologicallimitvalues No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Use explosion-proof ventilation equipment to stay below exposure limits. Adequate ventilation
should be provided so that exposure limits are not exceeded. Individual protection measures, such as personal protectiveequipment Eye/faceprotection Wear safety glasses with side shields (or goggles).
Skin protection Handprotection Chemical resistant gloves.
Other Not available. Respiratoryprotection Respiratory protection not required. If ventilation is insufficient, suitable respiratory protection must be provided. Thermal hazards Wear appropriate thermal protective clothing, when necessary.
Generalhygieneconsiderations When using do not smoke. Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Refer to Spec Sheet Physical state Liquid. Form Liquid. Color Refer to Spec Sheet
Odor Characteristic.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initialboilingpointandboiling 446 - 447.8 °F (230 - 231 °C)
range Flashpoint 199.0 °F (92.8 °C) Closed Cup Evaporation rate Not available. Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits Flammability limit -lower Not available. (%)

SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 5 of 10 Print Date: 02-20-2018

Flammability limit -upper Not available. (%) Explosive limit -lower (%) Not available. Explosive limit -upper (%) Not available. Vapor pressure 0.07 mm Hg at 25 °C Vapor density 5.2 Relative density Not available. Solubility(ies)
Solubility (water) Insoluble Partition coefficient Not available. (n-octanol/water)
Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Otherinformation
Explosive properties Not explosive. Flammability class Combustible IIIB estimated Molecular formula C10H15N Molecular weight 149.24 g/mol Oxidizing properties Not oxidizing. Specificgravity 0.91 at D20/4
10. STABILITYAND REACTIVITY Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemicalstability Material is stable under normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions Conditionstoavoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatiblematerials Strong oxidizing agents.
Hazardousdecomposition No hazardous decomposition products if stored and handled as indicated.
products
11. TOXICOLOGICAL INFORMATION Information on likely routes ofexposure
Inhalation No adverse effects due to inhalation are expected.
Skin contact Causes skin irritation.
Eye contact Direct contact with eyes may cause temporary irritation. Causes mild eye irritation.
Ingestion May be harmful if swallowed.


SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 6 of 10 Print Date: 02-20-2018

Symptoms related to the Skin irritation. May cause redness and pain. physical, chemical and toxicological characteristics
Information on toxicological effects
Acute toxicity May be harmful if swallowed.
Product Species Test Results
2,2,3-Trimethylcyclopent-3- enylacetonitrile (CAS 15373-31-6) Acute Oral LD50 Rat > 2000 mg/kg
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer. Skinsensitization This product is not expected to cause skin sensitization. Germcellmutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity
IARC Monographs. Overall Evaluation ofCarcinogenicity Not listed. OSHASpecifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US. National Toxicology Program(NTP) Report onCarcinogens Not listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not available. Reproductivetoxicity This product is not expected to cause reproductive or developmental effects. Specifictargetorgantoxicity -Not classified.
single exposure
Specifictargetorgantoxicity -Not classified. repeated exposure
Aspiration hazard Not an aspiration hazard.
12. ECOLOGICALINFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this substance. Bioaccumulativepotential No data available. Mobilityinsoil No data available.

SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 7 of 10 Print Date: 02-20-2018

Otheradverseeffects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. DISPOSALCONSIDERATIONS
Disposalinstructions Do not discharge into drains, water courses or onto the ground. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.
Localdisposalregulations Dispose in accordance with all applicable regulations.
Hazardouswastecode Not established.
Wastefromresidues/unused Empty containers or liners may retain some product residues. This material and its container must
products be disposed of in a safe manner (see: Disposal instructions). Contaminatedpackaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. TRANSPORTINFORMATION ADN Not regulated as dangerous goods. ADR Not regulated as dangerous goods. RID Not regulated as dangerous goods. DOT BULK UN number NA1993 Proper shipping name COMBUSTIBLE, LIQUID, N.O.S. (TRIMETHYL-3-CYCLOPENTENYLACETONITRILE) Hazard class Combustible liq Packing group III Environmental hazards Marine pollutant No Packaging exceptions 150 Packaging bulk 241 Labels required None
DOT NON-BULK
Not regulated as dangerous goods. IATA
Not regulated as dangerous goods. IMDG
Not regulated as dangerous goods.

SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 8 of 10 Print Date: 02-20-2018

15. REGULATORY INFORMATION USfederalregulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. CERCLA Hazardous Substance List (40 CFR302.4) Not listed. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not available. OSHASpecifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. TSCA Section 12(b) Export Notification (40CFR 707, Subpt. D) Not regulated. Superfund Amendments andReauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical Classifiedhazard Flammable (gases, aerosols, liquids, or solids) categories Acute toxicity (any route of exposure) Skin corrosion or irritation
SARA 313 (TRI reporting) Not regulated.
Otherfederal regulations Clean Air Act(CAA)Section112Hazardous AirPollutants (HAPs) List Not regulated. Clean Air Act(CAA)Section112(r) Accidental Release Prevention(40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US stateregulations California Proposition 65 California Proposition 65 -Carcinogens& Reproductive Toxicity (CRT): Listed substance Not listed. International Inventories
Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No

SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 9 of 10 Print Date: 02-20-2018

Country(s) or region Inventory name On inventory (yes/no)*
Europe European Inventory of Existing Commercial Chemical No
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
Taiwan Taiwan Toxic Chemical Substances (TCS) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).
16. OTHER INFORMATION,INCLUDING DATE OF PREPARATION OR LASTREVISION Issue date 12-01-2015 Revisiondate 02-20-2018 Version # 03 HMIS®ratings Health: 2
Flammability: 2 Physical hazard: 0
Disclaimer Vigon International, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The above information relates only to this product and not to its use in combination with any other material or any particular process and is designed only as guidance for the safe handling, use, processing, storage, transportation, and disposal and should not be considered as a guarantee or quality specification. This product has not been evaluated for safe use in e-cigarettes or any vaping application where the product(s) is/are intentionally vaporized and inhaled. Vigon International, Inc. has performed no testing on these products in e-cig/vaping applications. It is the sole responsibility of the individual(s) purchasing this product to assess its’ safety in the final application. The above information relates only to this product and not to its use in combination with any other material or any particular process and is designed only as guidance for the safe handling, use, processing, storage, transportation, disposal, and should not be considered as a guarantee or quality specification. The above information is based on data provided by and collected from recognized sources such as distributors, manufacturers, and technical groups and is considered to be accurate to the best of Vigon’s knowledge as of the date of this document. It is the responsibility of the user to review all safety information about this product and determine its safety and suitability in their own processes and operations. Appropriate warnings and safe handling procedures should be provided to all handlers and users, taking into account the intended use and the specific conditions and factors relating to such use in accordance with all applicable laws and regulations.

SAFETY DATA SHEET
502470 CANTRYL®
Revision Date: 02-20-2018 Version # 03 Page 10 of 10 Print Date: 02-20-2018

Revisioninformation Product and Company Identification: Vigon Values IDENTIFICATION: Recommended restrictions HAZARD(S) IDENTIFICATION: Prevention HAZARD(S) IDENTIFICATION: Response COMPOSITION/INFORMATION ON INGREDIENTS: Component information EXPOSURE CONTROLS/PERSONAL PROTECTION: Appropriate engineering controls Physical & Chemical Properties: Multiple Properties Toxicological Information: Toxicological Data TOXICOLOGICAL INFORMATION: Carcinogenicity ECOLOGICAL INFORMATION: Persistence / degradability Regulatory Information: United States REGULATORY INFORMATION: California Proposition 65 OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: Reference s OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION: Disclaimer