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SAFETY DATA SHEET
Issue Date: Dec 13, 1995                         Revision Date: Mar 21, 2013
SDS #: BRI410                                    Printed: May 16, 2013 17:48:03

Product #: 410       APRITONE

________________________________________________________________________________
SECTION 1.  PRODUCT AND COMPANY IDENTIFICATION 

Bedoukian Research, Inc.              Emergency Phone Numbers:
21 Finance Drive                      1-800-424-9300  Chemtrec (North America) 
Danbury, CT 06810-4133                1-703-527-3887  Chemtrec (International) 
UNITED STATES                      
Phone: 1-203-830-4000 Email: customerservice@bedoukian.com            
Fax:   1-203-830-4010 Website: http://www.bedoukian.com               

    Product Code: 410     
    Product Name: APRITONE
    Uses: flavors and fragrances
________________________________________________________________________________
SECTION 2.  HAZARDS IDENTIFICATION 

  HMIS HAZARD CLASSIFICATIONS
        HEALTH = 1    FLAMMABILITY = 1    REACTIVITY = 0    PROTECTION = B

  LABEL PRECAUTIONARY STATEMENTS
  GHS CLASSIFICATION AND LABELLING
    The following determinations per the Globally Harmonized System of
    Classification and Labelling of Chemicals (GHS) have been made:
  GHS SIGNAL WORD
    Warning
  GHS SYMBOLS
    GHS07 Exclamation mark
  GHS LABELING/HAZARD STATEMENTS
    H315 Causes skin irritation
  GHS LABELING/PRECAUTIONARY STATEMENTS
    P264 Wash hands thoroughly after handling.
    P280 Wear protective gloves/protective clothing/eye protection/face
    protection.
    P302+P352 IF ON SKIN: Wash with plenty of soap and water.
    P332+P313 If skin irritation occurs: Get medical advice/attention.
    P362 Take off contaminated clothing and wash before reuse.
________________________________________________________________________________
SECTION 3.  COMPOSITION/INFORMATION ON INGREDIENTS 

    CAS #:  68133-79-9   
    FEMA #: Approved
    MF:     C15H24O     
    EC NO:  268-706-3 
    Minimum Purity: 96.5% (sum of isomers)
    Additives: synthetic alpha tocopherol @ 0.10%
  SYNONYM(S)
    Cyclopentanone, 2-(3,7-dimethyl-2,6-octadienyl)-
    2-(3,7-Dimethyl-2,6-octadienyl)cyclopentanone
    2-(3,7-dimethyl-2,6-octadien-1-yl)-Cyclopentanone
    2-(3,7-dimethylocta-2,6-dienyl)cyclopentan-1-one
    Decenyl Cyclopentanone
    Geranyl Cyclopentanone
________________________________________________________________________________
SECTION 4.  FIRST-AID MEASURES 

    INHALATION EXPOSURE: Remove to fresh air. Give oxygen and call a physician.
    EYE CONTACT: Flush with water for 15 min. Seek medical help if necessary.
    SKIN CONTACT: Wash area well with water. Seek medical help if necessary.
    INGESTION: Administer water and call a physician or poison control
    center immediately.  Do not induce vomiting.
________________________________________________________________________________
SECTION 5.  FIRE FIGHTING MEASURES 

  EXTINGUISHING MEDIA
    CO2, FOAM, DRY CHEMICAL
  SPECIAL FIRE FIGHTING PROCEDURES
    Use standard fire fighting procedures.
  UNUSUAL FIRE AND EXPLOSION HAZARDS:
    None.
________________________________________________________________________________
SECTION 6.  ACCIDENTAL RELEASE MEASURES 

  STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
    Standard absorbents can be used.
  WASTE DISPOSAL METHOD: Incineration or sanitary landfill in
    accordance with local, state, and federal regulations.
________________________________________________________________________________
SECTION 7.  HANDLING AND STORAGE 

  HANDLING
    Observe all warnings and precautions listed for the product.
    Use in accordance with good manufacturing and industrial 
    hygiene practices. Use product in a properly ventilated work
    area. Do not eat, drink or smoke while handling product.
  STORAGE
    Packaging: Glass, Plastic, Aluminum or Phenolic Lined Steel
    Store tightly sealed under inert gas in a cool, well-ventilated area.
  FIRE PROTECTION
    Keep away from heat, sparks, and open flame.
________________________________________________________________________________
SECTION 8.  EXPOSURE CONTROLS/PERSONAL PROTECTION 

    VENTILATION: Local exhaust preferred. General ventilation required.      
    RESPIRATORY: Usually not required.  Avoid inhaling concentrated vapors.  
    SKIN: Avoid skin contact.  Use chemical resistant gloves.         
    EYES: Splash-proof safety glasses or goggles.                     
    OTHER PROTECTIVE EQUIPMENT: Safety shower, eye wash                                     
________________________________________________________________________________
SECTION 9.  PHYSICAL AND CHEMICAL PROPERTIES 

    PHYSICAL STATE: Liquid
    APPEARANCE: colorless liquid                   
    ODOR DESCRIPTION: peach-apricot, with jasmine undertones. 
    BOILING POINT: 310.79 C (EPI 4.0)
    VAPOR PRESSURE : 0.000887 mmHg (20C, EPI 4.0)  
    VAPOR DENSITY (Air = 1): > 1     
    SPECIFIC GRAVITY @ 25C (water = 1): 0.9110:0.9160
    SOLUBILITY IN WATER: Insoluble in water; soluble in alcohol. 
    FLASH POINT (CC):  230 F    110 C
    LOGP : 5.150
________________________________________________________________________________
SECTION 10. STABILITY AND REACTIVITY 

  INCOMPATIBILITIES
    CONDITIONS TO AVOID: Presents no special reactivity hazard.      
    MATERIALS TO AVOID: Strong oxidizing agents
  HAZARDOUS COMBUSTION PRODUCTS
    CO, CO2, water                         
________________________________________________________________________________
SECTION 11. TOXICOLOGICAL INFORMATION 

  ACUTE EFFECTS
    Most likely route of entry is through the skin.
    Full strength may be irritating to skin and eyes.
  IFRA RECOMMENDATIONS
    This product contains material that has an IFRA standard.
    Please visit www.ifraorg.org for the full text of the guideline for the
    material indicated.
    This product contains material with an IFRA standard.  This material and
    its amount in the formulation are as follows:
    beta-Damascone (a Rose ketone) up to 0.05%.
  IRRITATION DATA
    Dermal sensitization (Guinea Pigs): Apritone is not a sensitizer. Buehler
    method; material tested at 100% concentration.
    Eye Rabbit: no irritant effects. Result for similar mat'l 2-(3,7-dimethyl-
    2,6-nonadien-1-yl)-Cyclopentanone
    Skin Rabbit: irritant effects, primary irritation index = 4.12.
  TOXICITY DATA
    LD50 Dermal (rabbit) > 5000 mg/kg. Result for similar mat'l 2-(3,7-
    dimethyl-2,6-nonadien-1-yl)-Cyclopentanone.
    LD50 Oral (rat) > 5 g/kg.
  OTHER DATA
    All components of this product are FEMA/GRAS or FDA approved for flavors.
    All components of this product are listed on the EU union list of
    flavourings as allowed for all categories of food.
    contains: up to 0.005% FEMA 3264; 0.03% FEMA 3410; 0.05% FEMA 3243; 0.06%
    FEMA 3937; 0.11% FEMA 3758; 99.9% FEMA 3829.
    contains: up to 0.005% z-4-Decenal; 0.03% Methyl jasmonate; 0.05% beta-
    Damascone; 0.06% Lactone of cis jasmone; 0.11% Jasmolactone extra C; 99.9%
    2-(3,7-Dimethyl-2,6-octadienyl)cyclopentanone
  THRESHOLD LIMIT VALUE (TLV): Not established
  OSHA PERMISSABLE EXPOSURE LIMIT (PEL): Not established
  LISTED AS CARCINOGEN BY NTP, IARC, OR OSHA?:  NO
________________________________________________________________________________
SECTION 12. ECOLOGICAL INFORMATION 

   GENERAL 
    Prevent contamination of soil, ground- and surface water.

________________________________________________________________________________
SECTION 13. DISPOSAL CONSIDERATION 

  WASTE DISPOSAL METHOD: Incineration or sanitary landfill in
    accordance with local, state, and federal regulations.
________________________________________________________________________________
SECTION 14. TRANSPORT INFORMATION 

                     Class    Pack Group    Sub. Risk    UN No.
________________________________________________________________________________
    Road(U.S.-DOT):  not regulated.
    Air (IATA):      not regulated.
    Sea (IMDG):      not regulated.
________________________________________________________________________________
SECTION 15. REGULATORY INFORMATION 

  REVIEWS, STANDARDS, AND REGULATIONS
    This chemical is listed on the following inventories:
    TSCA AICS CHINA DSL EINECS(268-706-3) PICCS 
    LISTED AS CARCINOGEN BY NTP, IARC, OR OSHA?:  NO
________________________________________________________________________________
SECTION 16. OTHER INFORMATION 

    DISCLAIMER OF WARRANTIES AND LIMITATION OF LIABILITY
      THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH
    WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED
    WITHOUT ANY WARRANTY, EXPRESS OR IMPLIED REGARDING ITS CORRECTNESS.
      BEDOUKIAN RESEARCH INC. ("BRI") MAKES NO REPRESENTATIONS OR WARRANTIES,
    EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
    PARTICULAR PURPOSE OR OF ANY OTHER NATURE WITH RESPECT TO THE
    INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS.
      BRI'S SOLE AND EXCLUSIVE LIABILITY WITH RESPECT TO PRODUCTS
    PROVIDED TO BRI'S SATISFACTION TO BE DEFECTIVE OR NONCONFORMING
    SHALL BE THE REPLACEMENT OF SUCH PRODUCTS WITHOUT CHARGE OR REFUND
    OF THE PURCHASE PRICE UPON THE RETURN OF SUCH PRODUCTS IN ACCORDANCE
    WITH BRI'S INSTRUCTIONS. THIS REMEDY, IN THE MANNER PROVIDED HEREIN,
    SHALL CONSTITUTE FULFILLMENT OF ALL LIABILITIES OF BRI, WHETHER BASED
    ON CONTRACT, TORT OR OTHERWISE WITH RESPECT TO, OR ARISING OUT OF THE
    PRODUCTS. BRI SHALL NOT BE LIABLE FOR ANY INCIDENTAL, CONSEQUENTIAL,
    CONTINGENT OR SPECIAL DAMAGES.